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Before 2013
71) R. Gutzler, C. Fu, A. Dadvand, Y. Hua, J. MacLeod, F. Rosei*, D. F. Perepichka*, Halogen bonds in 2D
supramolecular self-assembly of organic semiconductors, Nanoscale 2012, 4, 5965–5971.
70) B. Djukic, D.F. Perepichka*, Unexpected formation of a cyclic vinylene sulfate in the synthesis of ethynylsubstituted acenes, Chem. Commun. 2012, 48, 6651–6653.
69) A. Dadvand, A.G. Moiseev, K. Sawabe, W.-H. Sun, B. Djukic, I. Chung, T. Takenobu, F. Rosei, D.F.
Perepichka*, Maximizing field-effect mobility and solid-state luminescence in organic semiconductors,
Angew. Chem.Int. Ed. 2012, 51, 3837-3841.
68) B. Djukic, D.F. Perepichka*, Non-classical heteroacenes: synthesis and properties of anthra[2,3-c:6,7-
c’]dithiophene derivatives, Chem. Commun. 2011, 47, 12619-12621.
67) R. Gutzler, O. Ivasenko, C. Fu, J. L. Brusso, F. Rosei*, D. F. Perepichka*, Halogen bonds as stabilizing
interactions in a chiral self-assembled molecular monolayer, Chem. Commun. 2011, 47, 9453–9455.
66) O. Lukoyanova, M. Lepeltier, M. Laferrière, D.F. Perepichka*, Donor-Acceptor Intermediates and LowBandgap Polymers by Electropolymerization of Thienoazaborines, Macromolecules 2011, 44, 4729–4734.
65) O. Gidron, A. Dadvand, Y.Sheynin, M. Bendikov,* D.F. Perepichka,* Towards “green” electronic materials.
pi-Oligofurans as Semiconductors, Chem. Commun. 2011, 1976–1979.
64) M. Kondratenko, A. Moiseev, D.F. Perepichka,* New stable donor-acceptor dyads for molecular electronics,
J. Mater. Chem. 2011, 21, 1470–1478.
63) O. Ivasenko, D.F. Perepichka*, Mastering fundamentals of supramolecular design with carboxylic acids.
Common lessons from X-ray crystallography and scanning tunneling microscopy, Chem. Soc. Rev. 2011, 40,
62) M. Lepeltier, O. Lukoyanova, A. Jacobson, D.F. Perepichka,* New azaborine-thiophene heteroacenes, Chem.
Comm. 2010, 2007–2009
61) C. Yan, A. Dadvand, F. Rosei, D. F. Perepichka,* NIR Photoresponse in New Up-converting
CdSe/NaYF4:Yb,Er nano-heterostructures, J. Am. Chem. Soc. 2010, 132, 8868–8869.
60) J.A. Lipton-Duffin, J.A. Miwa, M. Kondratenko, F.Cicoira, B. G. Sumpter, V. Meunier*, D.F. Perepichka*,
F. Rosei*, Step-by-step growth of aligned polythiophene wires by surface-confined oligomerization, Proc.
Nat. Acad. Sci. USA 2010, 107, 11200–11204.
59) S. Jeeva, O. Lukoyanova, A. Karas, A. Dadvand, F. Rosei, D.F. Perepichka*, New highly emissive thienylenevinylene oligomers and co-polymers for organic electronics, Adv. Funct. Mater. 2010, 20, 1661–1669.
58) C. Yan, L. Nikolova, A. Dadvand, C. Harnagea, A. Sarkissian, D. F. Perepichka,* D. Xue,* F. Rosei*,
Multiple NaNbO3/Nb2O5 nanotubes: a new class of semiconductor heterostructures, Adv. Mater. 2010, 22,
57) A. Demenev, S. H. Eichhorn*, T. Taerum, D. F. Perepichka*, S. Patwardhan, F. C. Grozema*, L.D.A.
Siebbeles, Quasi temperature independent charge carrier mobility in hexagonal columnar mesophases of Hbonded benzotristhiophene derivative, Chem. Mater. 2010, 22, 1420–1428.
56) J. M. MacLeod, O. Ivasenko, C. Fu, T. Taerum, F. Rosei*, D.F.Perepichka*, Supramolecular ordering in
oligothiophene-fullerene monolayers studied by STM, J. Am. Chem. Soc. 2009, 131, 16844–16850.
55) T. Taerum, O. Lukoyanova, R. Wylie, D. F. Perepichka*, Synthesis, polymerization and unusual properties
of new star-shaped thiophene oligomers, Org. Lett. 2009, 11, 3230–3233.
54) M. Lepeltier, J. Hiltz, T. Lockwood, F. Bélanger-Gariépy, D.F. Perepichka*, Towards crystal engineering of
solid state polymerization in dibromothiophenes, J. Mater. Chem. 2009, 19, 5167–5174.
53) F. Vetrone, F. Variola, P. Tambasco de Oliveira, S. F. Zalzal, J.-H. Yi, J. Sam, A. Sarkissian, D.F.
Perepichka, J. D. Wuest, F. Rosei, A. Nanci*, Nanoscale oxidative patterning of metallic surfaces to
modulate cell activity and fate, Nano Lett. 2009, 9, 659–665.
52) J. A. Lipton-Duffin, O. Ivasenko, D. F. Perepichka*, F. Rosei*, Synthesis of polyphenylene molecular wires
by surface confined polymerization, Small 2009, 5, 592–597
51) F. Variola, F. Vetrone, L. Richert, P. Jedrzejowski, J.H. Yi, S. Zalzal, S. Clair, A. Sarkissian, D.F. Perepichka,
J.D. Wuest, F. Rosei, A. Nanci*, Improving biocompatibility of materials by nanoscale modification of
surfaces: an overview of strategies, fabrication methods and challenges, Small, 2009, 5, 996–1006 (refereed
50) D. F. Perepichka*, F. Rosei*, Extending polymer conjugation in the second dimension, Science 2009, 323,
216–217. (refereed Highlight)
49) O. Ivasenko, J. M. MacLeod, ?. Chernichenko, E. Balenkova, R. V. Shpachenko, V. G. Nenajdenko, F. Rosei*,
D. F. Perepichka*, Supramolecular assembly of heterocirculenes in 2D and 3D, Chem. Commun., 2009,
48) A. Dadvand, F. Cicoira, K. Yu. Chernichenko, E. S. Balenkova, R. M. Osuna, F. Rosei, V. G. Nenajdenko, D.
F. Perepichka*, Heterocirculenes as a new class of organic semiconductors, Chem. Commun. 2008, 5354–
47) J. A. Miwa, F. Cicora, J. Lipton-Duffin, D. F. Perepichka, C. Santato, F. Rosei*, Self-assembly of rubrene on
Cu(111), Nanotechnology 2008, 19, 424021.
46) J. A. Miwa, F. Cicoira, S. Bedwani, J. Lipton-Duffin, D. F. Perepichka, A. Rochefort, F. Rosei*, Self-assembly
of rubrene on copper surfaces, J. Phys. Chem. C. 2008, 112, 10214–10221.
45) S. Clair, F. Variola, M. Kondratenko, P. Jedrzejowski, A. Nanci, F. Rosei*, D.F. Perepichka*, Self-assembled
monolayer of alkanephosphoric acid on nanotextured Ti, J. Chem. Phys. 2008, 128, 144705.
44) J. L. Brusso, O. Hirst, A. Dadvand, S. Ganesan, F. Cicoira, C. M. Robertson, R. T. Oakley, F. Rosei, D. F.
Perepichka*, A New Structural Motif in Thienoacene Semiconductors: Synthesis, Structure and Properties of
Tetrathienoanthracene Isomers, Chem. Mater. 2008, 20, 2484–2494.
43) D. F. Perepichka*, I. F. Perepichka*, O. Ivasenko, A J. Moore,M. R. Bryce*, L. G. Kuz’mina, A.S. Batsanov,
N.I. Sokolov, Combining High Electron Affinity and Intramolecular Charge Transfer in Nitrofluorene – 1,3-
Dithiole Push-Pull Diads, Chem. Eur. J. 2008, 14, 2757–2770.
8 Perepichka
42) F. Cicoira, C. Santato, A. Dadvand, C. Harnagea, A. Pignolet, P. Bellutti, Z. Xiang, F. Rosei*, H. Meng*, D.F.
Perepichka*, Environmentally stable organic light emitting field effect transistors based on 2-(4-
pentylstyryl)tetracene, J. Mater. Chem. 2008, 18, 158–161.
41) F. Cicoira, J. A. Miwa, D. F. Perepichka, F. Rosei*, Molecular assembly of rubrene on a metal/metal oxide
nanotemplate, J. Phys. Chem. A 2007, 111, 12647–12678.
40) K.G. Nath, O. Ivasenko, J.L. Macleod, J.A. Miwa, J.D. Wuest, A. Nanci, D.F. Perepichka*, F. Rosei*, Crystal
engineering in two dimensions: an approach to molecular nanopatterning, J. Phys. Chem. C 2007, 111, 16996–
39) J. M. Macleod, O. Ivasenko, D. F. Perepichka*, F. Rosei*, Stabilization of exotic minority phases in a
multicomponent self-assembled molecular network, Nanotechnology 2007, 18, 424031.
38) D.F. Perepichka*, F. Rosei*, Metal nanoparticles: from “artificial atoms” to “artificial molecules”, Angew.
Chem. Int. Ed. 2007, 46, 6006–6008. (refereed Highlight)
37) K.G. Nath, O. Ivasenko, J. A. Miwa, H. Dang, J. D. Wuest, A. Nanci, D. F. Perepichka*, F. Rosei*, Rational
modulation of the periodicity in linear hydrogen-bonded assemblies of trimesic acid on surfaces, J. Am. Chem.
Soc. 2006, 128, 4212–4213. (top 1% in citation in chemistry)
36) S. Amriou, C. Wang, A. S. Batsanov, M. R. Bryce*, D. F. Perepichka, E. Ortí, R. Viruela, J. Vidal-Gancedo,
C. Rovira, The interplay of inverted redox potentials and aromaticity in the oxidized states of new electron
donors, Chem. Eur. J. 2006, 12, 3389–3400.
35) Z. Wei, M. Kondratenko, L.H. Dao, D.F. Perepichka*, Rectifying diodes from asymmetrically functionalized
single wall carbon nanotubes, J. Am. Chem. Soc. 2006, 128, 3134–3135.
34) D.F. Perepichka*, F. Rosei*, Silicon nanotubes, Small 2006, 2, 22–25. (refereed Highlight)
33) D.F. Perepichka*, M. Kondratenko, M.R. Bryce, Self-assembled monolayers of strong electron acceptors:
polynitrofluorenes on gold and platinum, Langmuir 2005, 21, 8824–8831.
32) Md.B.Zaman, D.F.Perepichka*, A new simple synthesis of poly(thiophene-methine)s, Chem. Commun. 2005,
31) I.F. Perepichka*, D.F. Perepichka*, H. Meng*, F. Wudl*, Light-emitting polythiophenes, Adv. Mater. 2005,
19, 2281–2305. (refereed Review)
30) D.F.Perepichka*, M.R.Bryce*, Molecules with exceptionally low HOMO–LUMO Gap, Angew. Chem. Int.
Ed. 2005, 44, 5370–5373. (refereed Highlight)
29) G.Ho, J.R.Heath*, M.Kondratenko, D.F.Perepichka*, K.Arseneault, M.Pezolet, M.R.Bryce, The first studies
of a tetrathiafulvalene-?-acceptor molecular rectifier, Chem. Eur. J. 2005, 11, 2914–2922. (cover page)
28) M.Bendikov*, F.Wudl*, D.F.Perepichka*, Molecular materials across fields: TTFs, fullerenes and acenes,
Chem. Rev. 2004, 104, 4891–4945. (refereed Review)
27) D.F.Perepichka*, F.Wudl*, S.R.Wilson*, Y.Sun, D.I.Schuster*, The dissolution of carbon nanotubes in
Aniline, Revisited, J. Mater. Chem. 2004, 14, 2479–2482.
26) H.Meng, D.F.Perepichka, M.Bendikov, F.Wudl*, G.Z.Pan, Y.Wenjiang, W.Dong, S.Brown, Solid-state
synthesis of a conducting polythiophene via an unprecedented heterocyclic coupling reaction, J. Am. Chem.
Soc. 2003, 125, 15151–15162.
25) D.F.Perepichka, M.R.Bryce*, C.Pearson, M.C.Petty, E.J.L.McInnes, J.P.Zhao, A covalent tetrathiafulvalene–
tetracyanoquinodimethane diad: extremely low HOMO–LUMO gap, thermoexcited electron transfer and high
quality Langmuir Blodgett films, Angew. Chem. Int. Ed. 2003, 42, 4635–4639. (inside cover)
24) A.S.Batsanov*, D.F.Perepichka, A 1:1 cocrystal of 2,7-dicyanomethylene-4,5-dinitrofluorene and
benzonitrile, Acta Cryst. 2003, E59, o1318–1320.
23) D.F. Perepichka, M. Bendikov, H. Meng, F. Wudl*, A one-step synthesis of a poly(iptycene) through an
unusual Diels-Alder cyclization/dechlorination of tetrachloropentacene, J. Am. Chem. Soc. 2003, 125, 10190–
22) M.R. Bryce, G. Cooke*, F.M.A. Duclairoir, P. John, D.F. Perepichka, N. Polwart, V.M. Rotello, J.F. Stoddart,
H.-R. Tseng, Electrochemically controllable surfaces with three-pole binding properties, J. Mater. Chem. 2003,
13, 2111–2117.
21) B. de Boer, H. Meng, D.F. Perepichka, J. Zheng, M.M. Frank, Y.J. Chabal, Z. Bao*, Synthesis and
characterization of conjugated mono- and dithiol oligomers and characterization of their self-assembled
monolayers, Langmuir 2003, 19, 4272–4284. (10 most requested in 2004 by CAS)
20) H. Meng, D. F. Perepichka, F.Wudl*, Facile solid state synthesis of a highly conducting
poly(ethylenedioxythiophene), Angew. Chem. Int. Ed. 2003, 42, 658–661. (VIP and cover page)
19) D.F.Perepichka, M.R.Bryce*, I.F.Perepichka, S.B.Lyubchik, N.Godbert, C.A.Christensen, A.S.Batsanov,
E.Levillain, E.J.L.McInnes, J.P.Zhao, The first observation of A?––D2+ species: an unusual electrochemistry of
(?-extended tetrathiafulvalene)–?–fluorene conjugate, J. Am. Chem. Soc. 2002, 124, 14227–14238.
18) M.Brettreich, M.Bendikov, S.Chaffins, D.F.Perepichka, O.Dautel, H.Duong, R.Helgeson, F.Wudl*, Synthesis,
X-ray structure, and properties of a tetra-benzannelated 1,2,4,5-cyclophane, Angew. Chem. Int. Ed. 2002, 41,
17) D.F.Perepichka, M.R.Bryce*, A.S.Batsanov, E.J.L.McInnes, J.P.Zhao, R.D.Farley, Engineering a remarkably
low HOMO–LUMO gap by covalent linkage of a strong pi-donor and pi-acceptor, Chem. Eur. J. 2002, 8, 4656–
16) A.S.Batsanov*, D.F.Perepichka, Methoxycarbonylmethyl 2-methoxycarbonyl-3-hydroxybenzo[b]furan-6-
carboxylate, Acta Cryst. 2002, E58, o1227–1228.
15) L.G.Kuz’mina, I.F.Perepichka*, D.F.Perepichka, J.A.K.Howard, M.R.Bryce*, Supramolecular architecture
for two charge-transfer complexes based on 2,7-(X,X)-4,5-dinitro-9-dicyanomethylenefluorenes (X = NO2 or
CN) with tetrathiafulvalene, Cryst. Reports 2002, 251–261.
14) D.F.Perepichka, M.R.Bryce*, A.S.Batsanov, J.A.K.Howard, A.O.Cuello, M.Gray, V.M.Rotello,
Trialkyltetrathiafulvalene-?-tetracyanoanthraquinodimethane (R3TTF-?-TCNAQ) diads: synthesis,
intramolecular charge-transfer properties and X-ray crystal structure, J. Org. Chem. 2001, 66, 4517–4524.
13) A.S.Batsanov, J.C.Collings, J.A.K.Howard, T.B.Marder*, D.F.Perepichka, Arene–perfluoronaphthalene
interactions in crystal engineering. 5. Octafluoronaphthalene–tetrathiafuvalene (1/1), Acta Cryst. 2001, C57,
12) D.F.Perepichka, I.F.Perepichka*, M.R.Bryce*, N.I.Sokolov, A.J.Moore, ?–Extended nitrofluorene-1,3-
dithiole chromophore: enhancing the photoresponse of holographic materials through the balance of
intramolecular charge transfer and electron affinity, J. Mater. Chem. 2001, 11, 1772–1774.
11) D.F.Perepichka, M.R.Bryce*, E.J.L.McInnes, J.P.Zhao, The first tetrathiafulvalene–?–polynitrofluorene
diads: low HOMO–LUMO gap, amphoteric redox behavior & CT properties, Org. Lett. 2001, 3, 1431–1434.
10) D.F. Perepichka, I.F. Perepichka*, M.R. Bryce*, A.J. Moore, N.I. Sokolov, Push-pull dithiole – fluorene
acceptors as electron transport materials for holography, Synth. Met. 2001, 121, 1487–1488.
9) A.J.Moore, A.Chesney, M.R.Bryce*, A.S.Batsanov, J.F.Kelly, J.A.K.Howard, I.F.Perepichka, D.F.Perepichka,
G.Meshulam, G.Berkovich, Z.Kotler, R.Mazor, V.Khodorkovsky, Synthesis, structures and non-linear optical
properties of novel D–?–A chromophores: intramolecular charge transfer from 1,3-dithiole or ferrocene
moieties to polynitrofluorene or dicyanomethylene moieties through conjugated spacers, Eur. J. Org. Chem.
2001, 2671–2687.
8) M.R.Bryce*, A.Green, A.J.Moore, D.F.Perepichka, A.S.Batsanov, J.A.K.Howard, I.Ledoux-Rak, M.González,
N.Martín, J.L.Segura, J.Garín, J.Orduna, R.Alcalá, B.Villacampa, Synthesis of conjugated tetrathiafulvalene
(TTF)–pi–acceptor molecules: intramolecular charge transfer and nonlinear optical properties, Eur. J. Org.
Chem., 2001, 1927–1935.
7) I.F.Perepichka*, D.F.Perepichka, S.B.Lyubchik, M.R.Bryce*, A.S.Batsanov, J.A.K.Howard, Electron
acceptors of the fluorene series. 13. 9-(5-Nitrofuran-2-ylidene)- and 9-(5-nitrothien-2-ylidene)-2,4,5,7-
tetranitrofluorenes: novel ?-extended electron acceptors. Synthesis, cyclic voltammetry, X-ray crystal
structures for the acceptor and its 4,5-dimethyltetrathiafulvalene complex, and the theoretical study, J. Chem.
Soc., Perkin Trans. 2, 2001, 1546–1551.
6) A.E.Jones, C.A.Christensen, D.F.Perepichka, A.S.Batsanov, A.Beeby, P.J.Low, M.R.Bryce*, A.W.Parker,
Photochemistry of the ?-extended 9,10-bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene system: generation
and characterisation of the radical cation, dication and derived products, Chem. Eur. J., 2001, 7, 973–978.
10 Perepichka
5) D.F.Perepichka, I.F.Perepichka*, A.F.Popov, M.R.Bryce*, A.S.Batsanov, A.Chesney, J.A.K.Howard,
N.I.Sokolov, Electron Acceptors of the Fluorene Series. Part 12. 9-(Metalloceneylidene)nitrofluorene
derivatives of Fc–NF, NF–Fc–NF, and NF–Rc–NF types, and the vinylogues Fc–?–NF: synthesis,
characterisation, intramolecular charge transfer, redox properties and X-ray structures for three fluoreneferrocene derivatives, J. Organometal. Chem. 2001, 637–639, 445–462.
4) I. F. Perepichka*, D. F. Perepichka, M. R. Bryce*, A. Chesney, A. F. Popov, V. Khodorovsky, L. Shapiro, Z.
Kotler, Push-pull fluorene acceptors with ferrocene donor moiety, – Synth. Met. 1999, 102, 1558–1559.
3) D. D. Mysyk, I. F. Perepichka*, D. F. Perepichka, M. R. Bryce*, A. F. Popov, L. M. Goldenberg, A. J. Moore,
Electron acceptors of the fluorene series. 9. Derivatives of 9-(1,2-dithiol-3-ylidene), 9-(1,3-dithiol-2-ylidene)-
, and 9-(1,3-selenathiol-2-ylidene)fluorenes: synthesis, intramolecular charge transfer and redox properties, J.
Org. Chem. 1999, 64, 6937–6950.
2) I. F. Perepichka*, L. G. Kuz’mina, D. F. Perepichka, M. R. Bryce*, L. M. Goldenberg, A. F. Popov, J. A. K.
Howard, Electron acceptors of the fluorene series. 7. 2,7-Dicyano-4,5-dinitro-9-X-fluorenes: synthesis, cyclic
voltammetry, charge transfer complexation with N-propylcarbazole in solution and X-Ray crystal structures of
two tetrathiafulvalene complexes, J. Org. Chem. 1998, 63, 6484–6493.
1) I.F. Perepichka*, D.F. Perepichka, M.R. Bryce*, L.M. Goldenberg, L.G. Kuz’mina, A.F. Popov, A. Chesney,
A. J. Moore, J. A. K. Howard, N. I. Sokolov, Fluorene acceptors with intramolecular charge-transfer from 1,3-
dithiole donor moieties: novel electron transport materials, Chem. Commun. 1998, 819–820.